High Temperature Oxidation of Carbon Monoxide and Methane in a Turbulent Flow Reactor

Abstract

The high temperature oxidation reactions of carbon monoxide and methane in oxygen-rich atmospheres have been studied in a turbulent flow reactor. Spatial chemical sampling and gas chromatographic analysis techniques were developed for these studies, and the experimental methods are directly extendable to investigations of higher hydrocarbon oxidations. Overall expressions were developed for the carbon monoxide and methane disappearance rates and for the appearance rate of carbon dioxide in the methane-oxygen reaction. These and other data were used to deduce the re;ative importance of several elementary reactions in the oxidation mechanisms. It was concluded that other reactions in addition to hydroxyl attack on methane are important in governing the methane disappearance rate in oxygen-rich, high temperature systems.

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Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1972
Accession Number
AD0746284

Entities

People

  • Frederick L. Dryer

Organizations

  • Princeton University

Tags

Communities of Interest

  • C4I
  • Energy and Power Technologies
  • Space
  • Weapons Technologies

DTIC Thesaurus Topics

  • Alkanes
  • Carbon Monoxide
  • Chemical Analysis
  • Chemical Kinetics
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Combustion
  • Dielectric Gases
  • Energy Transfer
  • Exothermic Reactions
  • Hydrocarbon Fuels
  • Materials Laboratories
  • Materials Science
  • Materials Testing
  • Rate Of Formation

Fields of Study

  • Chemistry

Readers

  • Combustion science or combustion engineering.