Spectroscopic Analysis of the Products from the Reaction of Omicron- Chlorobenzylidenemalononitrile (CS) and 2-Diethylaminoethyl Mercaptan (DEAEM)

Abstract

Ultraviolet, infrared, and Raman spectra have been determined for the products of the reaction of o-chlorobenzylidenamalononitrile (CS) and 2- diethylaminoethyl mercaptan (DEAEM). Structures for two of the products, CS(DEAEM)2 and (CS)2DEAEM, are given, and their spectral characteristics are discussed. Reactions were followed in the ultraviolet by observing the changes occurring in the spectrum with time. The order of addition to CS in the case of the product CS(DEAEM)2, as observed by ultraviolet, is first, the addition to the double bond, and second, addition to the nitrile.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1972
Accession Number
AD0746639

Entities

People

  • Irwin Master
  • Ronald J. Piffath
  • Samuel Sass

Tags

Communities of Interest

  • C4I

DTIC Thesaurus Topics

  • Absorption
  • Absorption Spectra
  • Alcohols
  • Chemical Synthesis
  • Chemistry
  • Chlorides
  • Hydrogen Bonds
  • Infrared Spectra
  • New York
  • Optical Materials
  • Organic Chemistry
  • Plastic Explosives
  • Raman Spectra
  • Spectra
  • Spectroscopy
  • Two Dimensional
  • Ultraviolet Spectra

Readers

  • Astronomy and Astrophysics.
  • Electrochemical Surface Science
  • Spectroscopy.