A Test of RRKM Theory. Rates of Decomposition in the Series of 2-n-Alkyl Radicals from C4 through C16.
Abstract
The rates of decomposition of chemically activated 2-n-alkyl radicals in the series C(4)-C(16) were measured by an internal comparison method at 300K in the pressure region centered at 0.01-0.1 torr. Activation was by H-atom addition to the appropriate alpha-olefin. The substrate species have a minimum energy of about 40 kcal/mole. The consequences of radical isomerization are discussed. A limitation of the present activation technique is illustrated. Theoretical Marcus-Rice rate constants agree well with the experimental values. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Aug 10, 1972
- Accession Number
- AD0746835
Entities
People
- Benton Seymour Rabinovitch
- Edward A. Hardwidge
- Robert C. Ireton
Organizations
- University of Washington