Temperature Measurements of the Coefficient of Translational Self-Diffusion of Molecules in Certain Pure Liquids,

Abstract

The pulse technology of NMR (spin-echo technology) is a very convenient method for measuring the coefficient D(t) of the translational self-diffusion of molecules in a liquid. The authors compare the rotational activation energies obtained by optical methods with the barriers characterized directly by thermal translation of motion of molecules. The self diffusion and intermolecular actions of the following compounds were studied: Benzene; Toluene; Xylene; Chlorobenzene; Cyclohexane; Choloroform; Ethylene dichloride; Acetone; Acetonitrile; Water; Aniline; Phenol; and Benzophenone.

Document Details

Document Type
Technical Report
Publication Date
May 18, 1972
Accession Number
AD0747610

Entities

People

  • A. Sh. Agishev
  • F. I. Samigullin

Organizations

  • National Air and Space Intelligence Center

Tags

DTIC Thesaurus Topics

  • Acetonitrile
  • Acyclic Hydrocarbons
  • Alkenes
  • Chemical Compounds
  • Chlorobenzene
  • Coefficients
  • Cyclic Hydrocarbons
  • Cyclohexanes
  • Diffusion
  • Energy
  • Ethylenes
  • Heat Of Activation
  • Hydrocarbons
  • Ketones
  • Molecules
  • Nitriles

Fields of Study

  • Chemistry

Readers

  • Molecular Photonics/Laser Physics
  • Organic Chemistry
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.