Investigation of a Series of Bipeperidines. VIII. The Synthesis of Diastereomers of 2.2' - Bipiperidine,

Abstract

2,2' - Bipiperidine was reduced by aluminium in an aqueous-alcoholic solution of alkali. 2-(Biperidil-2) pyridine was obtained, the hydrogenation of which with sodium in isoamyl alcohol led to the formation of the erythro - and threo - isomers of 2,2' - bipiperidine. The separation of isomers was achieved by N,N' - diacetyl derivatives. (Author)

Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1972
Accession Number
AD0747719

Entities

People

  • Yu. I. Forstyan

Tags

DTIC Thesaurus Topics

  • Aluminum
  • Chemical Compounds
  • Chemical Reactions
  • Diastereomers
  • Elements
  • Group 13 Elements
  • Hydrogenation
  • Isomers
  • Metals
  • Molecules
  • Pyridines

Fields of Study

  • Chemistry

Readers

  • Analytical Chemistry
  • Organic Chemistry