Low Temperature Electrochemical Systems.

Abstract

Zinc-air batteries are subject to a marked decrease in performance at low temperature operation. Therefore, a detailed study of the pertinent parameters influencing air cathode behavior at reduced temperatures has been initiated. A series of electrode materials of different composition and physical characteristics has been used for the study. The electrochemical investigation included temperature studies of the charge transfer process occurring in the activation-controlled region of the O(2-) in the diffusion region. Real surface area determinations were made by two different methods: H2-deposition and BET measurements. The results obtained show that the major effect of temperature reduction is a decrease in transport-controlled currents.

Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1972
Accession Number
AD0749270

Entities

People

  • Kathleen Cahill
  • Paul A. Malachesky

Tags

DTIC Thesaurus Topics

  • Charge Transfer
  • Diffusion
  • Electrodes
  • Low Temperature
  • Materials
  • Measurement
  • Metal Air Batteries
  • Transport Ships
  • Two-Dimensional Materials

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Systems Analysis and Design
  • Thermal Physics or Thermal Science.