IR-Spectroscopy Investigation of the Mechanism for Grafting Styrene and Vinyl Acetate to Chlorinated Polyvinyl Chloride,

Abstract

When polyvinyl chloride is subjected to relatively high doses of irradiation one observes intermolecular interaction with splitting off of HCl (cross-linking of the polymer) and also the process of intramolecular splitting of HCl with the formation of a C=C-bond. Because the chlorinated PVC resin used is the product of chlorination of PVC, the authors investigated infrared spectroscopy as a means to clarify the mechanism by which styrene and vinyl acetate are grafted to it under relatively small doses of irradiation. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jun 30, 1972
Accession Number
AD0749537

Entities

People

  • P. P. Larin
  • R. S. Tillaev
  • S. A. Tashmukhamedov

Organizations

  • National Air and Space Intelligence Center

Tags

DTIC Thesaurus Topics

  • Chlorides
  • Chlorination
  • Chlorine Compounds
  • Infrared Spectroscopy
  • Plastics
  • Polymers
  • Polyvinyls
  • Resins
  • Spectroscopy
  • Splitting
  • Ultraviolet Spectroscopy

Readers

  • Nuclear and Radiation Engineering.
  • Organic Chemistry
  • Polymer Science and Technology