The Investigation of Organic Sulfur and Phosphorus Compounds as Additives for Lubricating Oils,

Abstract

It was found that the properties of thiophosphates are influenced strongly by the size of the radical connected with the thiol sulfur. The larger the radical the higher the thermo-oxidative stability, and for O,O-dialkyl-S-alkyldithiophosphates the lower the antiwear properties of the compounds. The following compounds were shown to be promising as multifunctional antiwear additives: trialkyltetrathiophosphates, bis-(O,)-dialkylthiophosphone)disulfides, and mixed ethers of thiophosphoric acids which contain nitrogen in the alkyl radical. The introduction of a trichloromethyl group into a molecule of dialkyldithiophosphates sharply intensifies their antiwear properties. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jun 30, 1972
Accession Number
AD0749638

Entities

People

  • A. P. Gupalo
  • I. L. Rabinovich
  • L. S. Kharchenko
  • T. P. Bachinskii
  • Yu. T. Gordash

Organizations

  • National Air and Space Intelligence Center

Tags

DTIC Thesaurus Topics

  • Additives (Chemicals)
  • Elements
  • Group 15 Elements
  • Lubricating Oils
  • Molecules
  • Nitrogen
  • Nonmetals
  • Phosphorus
  • Phosphorus Compounds

Fields of Study

  • Chemistry

Readers

  • Mathematics or Statistics
  • Organic Chemistry
  • Petroleum Engineering