On a Direct Relation between Nuclear Magnetic Resonance Chemical Shifts and Thermodynamic Excess Quantitities in Binary Systems with a Self-Associating Component,
Abstract
Based on the theory of the ideal associated mixture, a linear relation is derived between the chemical shift of protons capable of hydrogen bond formation and the ratio of the activity coefficients of the self-associating and the inert components of the mixture. Applicability and limits of the model are demonstrated using a series of alcohols in tetrachloromethane as examples. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Aug 17, 1972
- Accession Number
- AD0749741
Entities
People
- Reiner Radegilia
- Wabfram Kohler
- Werner Storek
Organizations
- National Air and Space Intelligence Center