1,3-Dipolar Addition Reactions of Some Bisdiazo Compounds with Mono and Diolefins

Abstract

Bisdiazoterephthalaldehyde, para-bisdiazobenzoylbenzene and meta-bis-diazobenzoylbenzene were synthesized as dicarbene precursors. Simultaneous dicarbene formation and olefinic insertion was attempted. However, what was observed was 1,3-dipolar addition of the bisdiazo compounds and strained olefinic systems such as norbornene and norbornadiene. Nuclear magnetic resonance spectroscopy indicates that the stereo-chemistry of the adducts formed lead to some large chemical shifts. Polymerization was also attempted between meta-bisdiazobenzoylbenzene and norbornadiene.

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1972
Accession Number
AD0750000

Entities

People

  • A. A. Volpe
  • R. J. Kricks

Organizations

  • Stevens Institute of Technology

Tags

Communities of Interest

  • Air Platforms

DTIC Thesaurus Topics

  • Addition Reactions
  • Chemical Engineering
  • Chemical Shifts
  • Chemical Synthesis
  • Chemistry
  • Hydrogen
  • Infrared Spectroscopy
  • Magnetic Resonance
  • Mass Spectra
  • Mass Spectroscopy
  • Materials
  • New Jersey
  • Nuclear Magnetic Resonance
  • Resonance
  • Spectra
  • Spectrometry
  • Spectroscopy

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry