Brain Acetylcholinesterase: Solubilization and Partial Purification by Affinity Chromatography.

Abstract

Guinea pig brain acetylcholinesterase was solubilized by addition of Triton X-100. Affinity chromatography was used to partially purify the solubilized enzyme. Two specific competitive inhibitors, para-carboxyphenyltrimethyl ammonium iodide and meta-carboxyphenyltrimethyl ammonium iodide, were synthesized. Sodium chloride, choline chloride, physostigmine, and pyridinium 2-aldoxime methiodide were used as eluants. Of the inhibitors synthesized, the meta-carboxyphenyltrimethyl ammonium iodide analog gave the better results. A sodium chloride elution followed by a linear gradient of choline chloride provided the best elution of the bound enzyme. The partially purified enzyme hydrolyzed 0.01 moles of 14C-acetylcholine per hour per milligram protein, a 1000-fold purification. (Author)

Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1972
Accession Number
AD0750111

Entities

People

  • Clarence A. Broomfield
  • Douglas W. Reichard
  • Henry I. Yamamura
  • Tommy L. Gardner

Tags

DTIC Thesaurus Topics

  • Acetylcholinesterases
  • Chemical Compounds
  • Chlorides
  • Chromatography
  • Enzymes
  • Inhibitors
  • Rodents
  • Sodium
  • Sodium Compounds

Fields of Study

  • Biology
  • Chemistry

Readers

  • Analytical Chemistry
  • Molecular and Cellular Biochemistry
  • Neurotoxicology