High-Temperature Polyamides from New Hexahydrobenzodipyrrole Monomers

Abstract

The Army has a high priority program to provide protective clothing to air and tank crewmen who are subject to possible exposure to intense heat and flame as a result of accident or enemy action. The paper reports on the synthesis of a new class of heterocyclic polyamides made possible by the successful synthesis and isolation of two new hexahydrobenzodipyrrole monomers. These newly prepared monomers reacted readily with diacid chlorides to form polyamides. A number of such polymers has been achieved with a selected group of diacid chlorides and a limited characterization by standard techniques provides data indicating that outstanding thermal properties are possible.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1972
Accession Number
AD0750380

Entities

People

  • John T. Stapler
  • Joseph Bornstein

Organizations

  • United States Army Soldier Systems Center

Tags

Communities of Interest

  • Human Systems

DTIC Thesaurus Topics

  • Alcohols
  • Body Weight
  • Chemical Reactions
  • Chlorides
  • Cold Water
  • Differential Thermal Analysis
  • Ethers
  • Glass Transition Temperature
  • High Temperature
  • Magnetic Resonance
  • Materials
  • Melting Point
  • Nuclear Magnetic Resonance
  • Spectra
  • Thermal Properties
  • Transition Temperature
  • Water

Fields of Study

  • Chemistry

Readers

  • Materials Science
  • Polymer Science and Technology
  • Systems Analysis and Design