The Synthesis of Phosphorus- and Sulphur-Containing Compounds and a Study of Their Action on the Quality of Lubricating Oils

Abstract

Compounds containing both S and P, giving good anticorrosion and detergency properties to lubricating oils and having good compatibility with other additives, were prepared by treating dialkyl dithiophosphates ((RO)2P(S) SH) with unsaturated compounds, e.g. MeCN, Me methacrylate, or vinyl acetate to give trialkyl dithiophosphates. They were also prepared by polymerizing paraffin or kerosene thermal cracking products, the residue from petroleum cracking, low molecular weight polymers, or isobutylene, treating the polymers with P2S5, and converting the products to their Ca, Ba, or Zn salts. A third method was by converting mixtures of dithiophosphate and dithiophosphonate diesters prepared from P2S5 and octyl alcohol, alkylphenols, and (or) polymer distillates to their An or Ba salts.

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1972
Accession Number
AD0750967

Entities

People

  • R. K. Mamedova
  • S. M. Abutalybova

Organizations

  • National Air and Space Intelligence Center

Tags

DTIC Thesaurus Topics

  • Additives (Chemicals)
  • Alkanes
  • Alkenes
  • Chemical Industry
  • Chemical Synthesis
  • Chemistry
  • Corrosion
  • Corrosion Inhibition
  • Cracks
  • Drug Abuse
  • Ethers
  • Foreign Technology
  • Hydrocarbons
  • Laboratory Tests
  • Lubricating Oils
  • Organic Compounds
  • Unsaturated Hydrocarbons

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Petroleum Engineering
  • Polymer Science and Technology