An Investigation of Yttrium Oxide as a Crucible Material for Melting Titanium

Abstract

The feasibility of using yttrium oxide as a crucible material for induction melting of titanium was investigated. Melting experiments using 10- and 30-gram capacity yttrium oxide crucibles led to the conclusion that molten titanium partially dissociates the yttrium oxide resulting in limited interstitial oxygen contamination of the titanium and in the formation of a titanium-yttrium-oxygen eutectic phase in the cast microstructure. Variation in the crucible density over the range of 70% to 97% of theoretical had no measurable effect on the extent of melt contamination. However, it was noted that melts prepared in oxygen deficient crucibles generally had the highest levels of contamination. Although up to 1.93% yttrium and 0.56% oxygen were picked up from the crucibles, comparison of the results reported in this investigation to those of previous studies on refractory oxides, indicates that yttrium oxide appears to be the best candidate crucible material for melting titanium.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1973
Accession Number
AD0754092

Entities

People

  • C. A. Zanis
  • David W Taylor
  • R. L. Helferich

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Chemistry
  • Energy
  • Free Energy
  • Graphitic Materials
  • Materials
  • Materials Processing
  • Measurement
  • Melting Point
  • Metals
  • Molybdenum
  • Oxides
  • Oxygen
  • Physical Properties
  • Thermodynamic Properties
  • Titanium
  • Transition Metals
  • Zirconium

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Powder metallurgy of Titanium alloys.