The Synthesis of 9-Vertex, Monocarbon, Metallocarboranes by Polyhedral Contraction.
Abstract
The base degradation of orange (pi-C5H5)Co(III)(pi-6,7-B10C2H12) has been found to effect a polyhedral contraction reaction to give ((pi-C5H5)Co(III)-(pi-2-B7CH8))(-1). This reaction constitutes the first reported example of a small metallocarborane formed by the removal of a carbon atom and three boron atoms from the polyhedral framework of a larger metallocarborane. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 08, 1972
- Accession Number
- AD0754477
Entities
People
- Donald F. Dustin
- M. Frederick Hawthorne
Organizations
- University of California, Los Angeles