Reduction of Sulfur Dioxide Using Microwave Discharge Techniques.

Abstract

Sulfur dioxide concentrations were reduced in a microwave discharge to investigate a possible system for industrial environmental application. An 85 watt, 2450 MHz microwave power generator and resonance cavity were used to sustain the discharge in a low pressure system. Static discharge tests were conducted with the time duration of discharge varied to determine the dependence of SO2 reduction on molecular residence time in the discharge. The reduction of pure SO2 in the discharge resulted in the formation of SO3 and elemental sulfur. The net reductions of SO2 was unacceptable for industrial applications, leading to discharge investigations of SO2 in mixtures with selected additive gases. Carbon dioxide (CO2) and Ethylene (C2H4) were found to be effective in improving the net reduction of SO2 in short-period (5-20 sec) discharges. Ethylene acted as an oxygen scavenger. Carbon dioxide acted as an oxygen donator. Results of the investigation indicated that the reduction of SO2 concentrations by means of a microwave discharge process has possibilities for industrial applications.

Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1971
Accession Number
AD0758788

Entities

People

  • Thomas D. Edmonds

Organizations

  • Air Force Institute of Technology

Tags

Communities of Interest

  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Additives (Chemicals)
  • Alkenes
  • Carbon Dioxide
  • Chemical Compounds
  • Dielectric Gases
  • Ethylenes
  • Gases
  • Generators
  • Microwaves
  • Resonance

Readers

  • Combustion science or combustion engineering.
  • Electrical Engineering
  • Pulsed Power and Plasma Physics.