The Intergranular Embrittlement of Nickel by Hydrogen.

Abstract

The mechanical behavior of polycrystalline nickel specimens that were deformed in tension and cathodically charged with hydrogen simultaneously was investigated with particular emphasis on the fracture of such electrodes. This procedure leads to very definite if, however, weak serrated yielding and also markedly reduces the elongation at fracture compared to polycrystals unexposed to hydrogen. Moreover, in contrast to hydrogenated nickel monocrystals which neck down to give a chisel-edge fracture typical of ductile metals, hydrogenated polycrystal fractures are brittle and intergranular. The embrittlement of nickel by hydrogen is shown by means of Auger electron spectroscopy to be associated with the segregation of hydrogen recombination poisons to the grain boundaries. (Author Modified Abstract)

Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1973
Accession Number
AD0759036

Entities

People

  • H. Opperhauser Jr.
  • R. M. Latanision

Organizations

  • Martin Marietta

Tags

DTIC Thesaurus Topics

  • Auger Electron Spectroscopy
  • Auger Electrons
  • Crystal Structure
  • Crystals
  • Electron Spectroscopy
  • Electrons
  • Embrittlement
  • Grain Boundaries
  • Hydrogen
  • Polycrystals
  • Spectroscopy

Fields of Study

  • Materials science

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Materials Science (Mechanical Engineering).
  • Materials Science and Engineering.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene