Study of the Tungsten Hydroquinone Color; Spectrophotometric Determination of Tungsten in Tungsten Steels.

Abstract

An investigation was made of the red color produced by tungsten and hydroquinone in a concentrated sulfuric acid medium. Various factors affecting the color were studied including the effect of phosphoric acid, water, hydrochloric acid, stannous chloride, and wave length at which the color is measured. The interference from iron, molybdenum, vanadium, and titanium was studied. A method is described for the determination of tungsten in tungsten steels that involves precipitation of the tungsten with cinchonine, ignition to tungstic oxide, dissolution of the tungstic oxide in sodium hydroxide, and development of the tungsten hydroquinone color on an aliquot of the solution. (Author)

Document Details

Document Type
Technical Report
Publication Date
Apr 01, 1973
Accession Number
AD0762122

Entities

People

  • George Norwitz
  • Herman Gordon

Organizations

  • Frankford Arsenal

Tags

DTIC Thesaurus Topics

  • Acids
  • Alkenes
  • Chemical Compounds
  • Chlorides
  • Dermatologic Agents
  • Elements
  • Hydrochloric Acid
  • Hydroxides
  • Ignition
  • Metals
  • Molybdenum
  • Phosphoric Acids
  • Precipitation
  • Refractory Metals
  • Sodium
  • Sodium Hydroxide
  • Tungsten

Readers

  • Analytical Chemistry
  • Materials Science and Engineering.