Nonlinear Absorption of Light by Solutions of Organic Dyes.

Abstract

Optical transitions between the quasistatic energy states of a solute organic dye are described using the coherent-interaction formalism. Expressions for the polarization and occupation state of a single molecule are averaged statistically to obtain rate equations for the absorption of light by an ensemble of molecules. The formalism developed in this report is used to describe spectral hole burning in organic dyes, as well as to investigate beam distortion that may arise during nonlinear attenuation. The formalism also leads to analytic expressions for the shape of organic-dye absorption and refractive-index spectra in terms of fundamental molecular parameters. An experimentally oriented chapter contains a review of past work on saturable absorption, and a description of research carried out in this laboratory on the ruby-laser Q-switch dye DDI. (Author)

Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1972
Accession Number
AD0762607

Entities

People

  • David W. Vahey

Organizations

  • California Institute of Technology

Tags

DTIC Thesaurus Topics

  • Absorption
  • Attenuation
  • Diffraction
  • Distortion
  • Equations
  • Lasers
  • Molecules
  • Polarization
  • Refractive Index
  • Ruby Lasers
  • Spectra
  • Transitions

Fields of Study

  • Physics

Readers

  • Chemistry (specifically Chemical Fluorescence)
  • Optical Physics and Photonics.
  • Plasma Physics / Magnetohydrodynamics

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers