Organometallic Amides and Imides.
Abstract
Reaction of LiN:C(CF3)2 or Me3SnN:C(CF3) with a Pt(II), Rh(I), or Ir(I) halide generally leads to the appropriate d8 metal alkylikeneamide (reactivity:Li>Me3Sn). A Pt(II) derivative, trans-Pt(N:C(CF3)2)(SnMe3)(PPh3)2 is also obtained by an oxidative addition of Me3SnN:C(CF3)2 to Pt(PPh3)2 (stilbene). trans-Pt(H or D)(N:C(CF3)2)(PPh3)2 rearranges into PtHN:C(CF3)2)(PPh3)2 by heating with PPh3 under reflux in benzene, or without phosphine in boiling xylene. The latter isomer reacts with an excess of PPh3 to give Pt(HN:C(CF3)2)(PPH3)3. The spectra of the new thermally- and hydrolytically-stable compounds, as well as the M-N cleavage by HCl, are discussed. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Nov 01, 1972
- Accession Number
- AD0763240
Entities
People
- B. Cetinkaya
- D. H. Harris
- Dorothy Palmer
- J. Mcmeeking
- M. F. Lappert
Organizations
- University of Sussex