Phosphinylmethyl Derivatives.
Abstract
Diphenylphosphinylmethanol, methylphenylphosphinylmethanol, and dimethylphosphinylmethanol have been prepared by fusion reactions of sodium acetate and the corresponding P, P-disubstituted chloromethylphosphine oxide at elevated temperatures followed by acid hydrolysis. The intermediate phosphinylmethyl acetates have been isolated and characterized. Both infrared and hydrogen nmr results show that there is extensive intramolecular hydrogen bonding in these phosphinylmethanols. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jun 01, 1971
- Accession Number
- AD0763693
Entities
People
- B. P. Block
- I. C. Popoff
- J. P. King