Chemical Reduction of 2.3,6-Trinitrotoluene (TNT) Initial Products

Abstract

High purity model compounds were needed for comparison with the products formed during the biodegradation of TNT. Thus, an attempt to prepare twelve reduction products of TNT (amino, hydroxylamino, azo and azoxy compounds) was made. Eight of these compounds were successfully prepared. Most of the compounds were synthesized according to literature procedures or modifications of literature procedures; however, two of the compounds prepared, 4,4',6,6'- tetranitro-2,2'-azoxytoluene and 2,4'-dimethyl-3,3',5,5'-tetranitro-ONN- azoxybenzene, have not previously been reported in the literature.

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Document Details

Document Type
Technical Report
Publication Date
Jun 14, 1973
Accession Number
AD0764060

Entities

People

  • Michael E. Sitzmann

Organizations

  • Naval Ordnance Laboratory

Tags

DTIC Thesaurus Topics

  • Alcohols
  • Azo Compounds
  • Chlorides
  • Chromatography
  • Column Chromatography
  • Gas Chromatography
  • Gels
  • Melting
  • Melting Point
  • Methylenes
  • Munitions
  • Nitrotoluenes
  • Ordnance Laboratories
  • Silica Gels
  • Spectra
  • Tnt
  • Toluenes

Readers

  • Agricultural Chemistry/Soil Science
  • Organic Chemistry