The Effect of Mercury and Tin from Aluminum Galvanic Anodes on the Corrosion Characteristics of 5086-H34 and 6061-T6 Aluminum Alloys in Seawater.

Abstract

Corrosion behavior studies were conducted in seawater for 696 days. There were no indications that corrosion products from either the Al-Hg-Zn or the Al-Sn-Zn galvanic anodes caused increased corrosion. Neither Hg nor Sn was found, by electron microprobe analysis, at corroded areas. The electron microprobe did reveal that the most severe localized corrosion occurred where copper, the source of which was unknown, had redeposited on the structural aluminum specimens. Cathodic protection from either the Al-Hg-Zn or the Al-Sn-Zn anodes virtually eliminated corrosion on the 5086-H34 and 6061-T6 aluminum specimens that were either continuously or alternately immersed in seawater, except for slight corrosion under some of the anodes. As expected, cathodic protection was only partially effective when it was provided for only the first 186 days of the 696 days of exposure. The slight corrosion and the buildup of bulky corrosion products between the anodes and the specimens confirmed the advisability of using some type of a barrier, such as zinc oxide paste or an organic coating, between aluminum anodes and the structure on which they are mounted. (Modified author abstract)

Document Details

Document Type
Technical Report
Publication Date
Nov 16, 1973
Accession Number
AD0771719

Entities

People

  • M. H. Peterson
  • R. E. Groover
  • T. J. Lennox Jr.

Organizations

  • United States Naval Research Laboratory

Tags

DTIC Thesaurus Topics

  • Abstracts
  • Alloys
  • Aluminum
  • Aluminum Alloys
  • Cathodic Protection
  • Coatings
  • Corrosion
  • Electrons
  • Microprobes
  • Organic Coatings

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Surface Engineering/Surface Coating Technology.
  • Systems Analysis and Design

Technology Areas

  • Microelectronics