Preparation and Properties of One-Dimensional Metals in Dielectric Matrices.
Abstract
The aim of this research was to prepare monocrystals of several compounds possessing metallic chains which are one-dimensionally or two-dimensionally constrained and evaluate their electronic properties. Such structures have been suggested to be possible models for high temperature superconductors. One-dimensional platinum complexes, and channel complexes of iodine and polysulfur nitrides were grown. Two-dimensional intercalation complexes and polymerization of monomeric Lewis bases were prepared. The superconducting critical temperature was determined by measuring ac magnetic susceptibility as a function of temperature. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Nov 01, 1973
- Accession Number
- AD0772741
Entities
People
- Mortimer M. Labes
- Vernon V. Walatka Jr
Organizations
- Temple University