High Energy Halogen Chemistry.
Abstract
The reaction of primary alkyl iodides with silver perchlorate gave mainly rearranged perchlorates in hydrocarbon or halocarbon solvents but unrearranged products in benzene. Silver triflate gave similar results. Alkyl iodides and dichlorine heptoxide gave alkyl perchlorates and an unidentified material that converted additional alkyl iodide to ether. Alkyl hypochlorites and iodine gave hypoiodites. Halogens and interhalogens reacted with olegins in the presence of dichlorine heptoxide or silver perchlorate to give beta-halo perchlorates. Reactions of alcohols, amines and ethers with dichlorine heptoxide are described. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 01, 1974
- Accession Number
- AD0773942
Entities
People
- Charles D. Beard
- Kurt Baum
- Vytautas Grakauskas