Inorganic Halogen Oxidizer Research.
Abstract
The authors have continued to study the use of PtF6 for the synthesis of novel, high-oxidation state species. Several XeF5(+) salts were characterized by 19F nmr and vibrational spectroscopy, and force fields were computed. A novel and interesting reaction between O2(+) salts and various halogen fluorides was discovered. A novel halogen perchlorate, the Cs(+)Br(ClO4)2(-) salt, was discovered and its structure was established by vibrational spectroscopy. A new and improved synthesis of anhydrous metal perchlorates was discovered. Investigation of synthetic methods for the preparation of the Rocketdyne discovered fluorocarbon perchlorates was continued. Work on the low-temperature ozonization of positive halogen compounds was completed. Numerous structural studies either have been completed or are under progress. The compounds studied include SF5Br, SF4, SF4O, ClF3O, CF3O(-), NF3O, and NF4(+) salts. (Modified author abstract)
Document Details
- Document Type
- Technical Report
- Publication Date
- Feb 26, 1973
- Accession Number
- AD0774925
Entities
People
- C. J. Schack
- D. Pilipovich
- E. C. Curtis
- K. O. Christe
- R. D. Wilson
Organizations
- Rocketdyne