Substituted Hydrazine Chemistry and Chemiluminescence in High Altitude Plumes

Abstract

Hydrazine and amine based fuels are shown to undergo highly exothermic oxidation reactions which can be a major source of infrared energy under conditions appropriate to high altitude plume afterburning. In low pressure, high oxygen atom environments, a single step, highly exothermic mechanism is capable of initiating the emission of infrared radiation. A specific set of reactions and energy transfer processes which characterize this potential emission are presented and an extensive review of the current literature related to amine oxidation is included. A flow field calculation directed toward testing the importance of chemiexcitation in amine afterburning is presented.

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1973
Accession Number
AD0776040

Entities

People

  • Edward R. Fisher
  • Frederick P. Boynton
  • Ralph H. Kummler

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Materials and Manufacturing Processes
  • Weapons Technologies

DTIC Thesaurus Topics

  • Afterburning
  • Air Force
  • Altitude
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Combustion
  • Combustion Products
  • Energy Transfer
  • Flow Fields
  • High Altitude
  • Hydrazines
  • Infrared Radiation
  • Infrared Signatures
  • Oxidation
  • Radiation

Fields of Study

  • Chemistry

Readers

  • Combustion and Flow Dynamics.
  • Organic Chemistry
  • Pulsed Power and Plasma Physics.