Certain Features of the Formation of Binary Chlorides of Alkali Metals in the Vapor State,
Abstract
The entropy was calculated for the dissociation of CsMcl2 to CsCl + MCl (M = alkali metal), assuming either a linear or a rhombic structure. The molecular parameters and vibration frequencies were found, rather grossly, from analogies. Comparison with experiment showed the real situation to be intermediate between the two proposed structures, indicating they may coexist, with the linear predominating soon and strongly for T above 1000K.
Document Details
- Document Type
- Technical Report
- Publication Date
- Dec 27, 1973
- Accession Number
- AD0776103
Entities
People
- A. B. Pospelov
- G. N. Novikov
Organizations
- United States Army Foreign Science and Technology Center