The Thermal Rearrangements of Non-Ichosahedral Cobaltacarboranes.

Abstract

The thermal rearrangements which isomerize the known isomers of non-icosahedral cobaltacarboranes of the type (eta-C5H5)CoC2BnH(n+2), n = 6, 7, 8, and 10, are discussed. A summary of conclusions regarding these rearrangements is presented as a set of empirical rules which seem to govern the migration of heteroatoms during thermal isomerizations. Kinetic data of some representative rearrangements are also discussed. (Author)

Document Details

Document Type
Technical Report
Publication Date
Feb 21, 1974
Accession Number
AD0776277

Entities

People

  • Christopher J. Jones
  • Donald F. Dustin
  • Henry Gong
  • Richard J. Wiersema
  • William J. Evans

Organizations

  • University of California, Los Angeles

Tags

DTIC Thesaurus Topics

  • Isomerization
  • Migration

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry