Vacuum UV Absorption Spectra Induced by Al(+) Ion Implantation in SiO2 Films on Sapphire.

Abstract

Measurements are reported on the vacuum ultraviolet absorption spectra induced in SiO2 films by Al(+) ion implantation. Studies have been made of the thermal stability of the associated defects and their response to X-irradiation subsequent to partial annealing. The implantation has been found to introduce an absorption band at 6.2 eV in films derived from the thermal decomposition of silane and at 7.5 eV in a fully oxidized S.O.S. film. In addition to introducing these vacuum ultraviolet absorption bands the implantation moves the fundamental absorption edge to lower energies. This band edge shift 'anneals' in parallel to the disappearance of the absorption bands and X-irradiation after a partial annealing is found to cause it to move towards lower energies again. This behavior is discussed in terms of the oxide structure. (Author)

Document Details

Document Type
Technical Report
Publication Date
Apr 22, 1974
Accession Number
AD0777967

Entities

People

  • B. S. H. Royce
  • T. J. Russell
  • T. Pandolif

Organizations

  • Princeton University

Tags

DTIC Thesaurus Topics

  • Absorption
  • Absorption Spectra
  • Annealing
  • Decomposition
  • Implantation
  • Ion Implantation
  • Ions
  • Measurement
  • Sapphire
  • Sorption
  • Spectra
  • Thermal Stability

Readers

  • Molecular Photonics/Laser Physics
  • Surface Engineering/Surface Coating Technology.