New 13-Atom Bimetallocarboranes Prepared by Polyhedral Subrogation.
Abstract
The reaction of 13-vertex cobaltacarbonanes, (eta-C5H5)-CoC2B10H12, with ethanolic postassium hydroxide in the presence of cyclopentadiene and an appropriate metal salt produces new 13-vertex bimetallllocarboranes. These bimetallic products, which may contain identical or dissimilar metals, have one less boron atom than does the original monometallocarborane. The preparation, characterization and structures of these complexes are discussed. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Apr 09, 1974
- Accession Number
- AD0777974
Entities
People
- Donald F. Dustin
- M. Frederick Hawthorne
Organizations
- University of California, Los Angeles