Diffusion of Scandium in Single Crystal Aluminum Oxide.

Abstract

The diffusion of scandium in single crystal aluminum oxide was studied using the Sc46 isotope as a radiotracer. An improved Gruzin method was used to determine the diffusion coefficients at various temperatures and oxygen partial pressures. The temperatures ranged between 1110C and 1465C. The oxygen partial pressures were 1 atmosphere and .0001 atmospheres. The dependence of the diffusion coefficient upon oxygen partial pressure was investigated to determine the type of mechanism controlling the diffusion of scandium in aluminum oxide. The dependence was observed to be very small. This tended to favor the Frenkl defect (formation of aluminum ion interstitials) mechanism as the primary controlling mechanism of the diffusion. (Modified author abstract)

Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1974
Accession Number
AD0780626

Entities

People

  • James E. Dockendorff

Organizations

  • Air Force Institute of Technology

Tags

DTIC Thesaurus Topics

  • Aluminum
  • Aluminum Oxides
  • Atmospheres
  • Coefficients
  • Crystals
  • Diffusion
  • Diffusion Coefficient
  • Oxides
  • Oxygen
  • Partial Pressure
  • Scandium
  • Single Crystals

Fields of Study

  • Materials science

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Surface Engineering/Surface Coating Technology.