Electrochemical Processes Associated with Energy Transfer.

Abstract

The reported project has had as its main theme study, on a broad front of research, the modes of energy transfer which can accompany electrochemically induced charge-transfer process. Significant aspects of electrochemical techniques, theory, instrumentation, developed during our studies of energy transfer modes have been (1) development of a computer controlled rapid scan stop flow kinetic spectrometer, (2) determination, using this spectrometer, of the kinetics and mechanism of an important and common electrochemical reaction sub-component, the protonation of a radical anion, (3) development of the theory for half-order regeneration reactions, a difficult-to-assess but perhaps common type of anodic electrode process, and (4) description of a new form of metal complex adsorption involving formation of adsorbed two-dimensional crystal phases. (Modified author abstract)

Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1974
Accession Number
AD0781272

Entities

People

  • Charles N. Reilley
  • Royce W. Murray

Organizations

  • University of North Carolina at Chapel Hill

Tags

Communities of Interest

  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Abstracts
  • Adsorption
  • Charge Transfer
  • Computers
  • Coordination Complexes
  • Electrochemical Reactions
  • Electrodes
  • Energy
  • Energy Transfer
  • Instrumentation
  • Kinetics
  • Measuring Instruments
  • Spectrometers
  • Two Dimensional

Fields of Study

  • Chemistry

Readers

  • Materials Science and Engineering.
  • Quantum Chemistry
  • Systems Analysis and Design