Reaction Products of Certain Derivatives of Difluorophosphoric Acid with Amines and Alcohols (Produkty Vzaimodeistviya Nekotoryk Proizvodnykh Diftorfosforistoi Kisloty s Aminami i Spirtami),
Abstract
The study of the reaction products of alkyldifluorophosphites and dialkylamido difluorophosphites with primary and secondary amines and alcohols yields the following results: Methyldifluorophosphite with ethyl--and isopropylamine yielded 3-coordinate (CH3O)2PF (an adduct of 2:1 with the corresponding primary amine) and the hydride of 5-coordinate phosphorus, RO(R'NH)PHF2. Methyldifluorophosphite with diethylamine also yields a 5-coordinate and a 3-coordinate compound--(C2H5)2NPF2 and CH3(C2H5)2NPF and (CH3O)2PF. Dimethylamidodifluorophosphite with isobutylamine yields a hydride of 5-coordinate phosphorus (CH3)2N(iso-C4H9NH)PHF2. Unstable hydrides (R2N)2PHF2 were formed in this reaction in the intermediate stages, just as they were in the reaction between alkyldifluorophosphine and the primary amines.
Document Details
- Document Type
- Technical Report
- Publication Date
- Aug 20, 1973
- Accession Number
- AD0784157
Entities
People
- C. Z. Ivin
- G. I. Drozd
- M. A. Landau
- M. A. Sokalskii
- V. V. Sheluchenko
Organizations
- United States Army Foreign Science and Technology Center