Novel Materials for Power Systems. Part 1. Schizophrenic Catalysts

Abstract

The oxidation of carbon monoxide and reduction of oxides of nitrogen over chromia catalysts supported on silica is currently under study. One might expect that if two otherwise identical catalysts were prepared with varied dispersions (chromium content being the same), that the reactivity would be different since the active sites, i.e., various stable surface oxidation states, may differ both in number and type. To test this simple hypothesis, a series of catalysts were prepared; series A by chromic acid impregnation and series B by chromium nitrate-oxalic acid complexing. Two series of catalysts with varied amounts of chromium were prepared to insure the existence of a region where the % Cr of both samples overlapped and where the catalyst activity as a function of % Cr could be examined.

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Document Details

Document Type
Technical Report
Publication Date
Jul 15, 1974
Accession Number
AD0784447

Entities

People

  • R. G. Squires

Organizations

  • Purdue University

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Carbon Monoxide
  • Chemical Synthesis
  • Chemistry
  • Chromic Acid
  • Crystal Lattices
  • Crystal Structure
  • Dielectric Gases
  • Electrons
  • Energy
  • Heat Of Activation
  • Mass Transfer
  • Materials
  • Measurement
  • Metal Oxides
  • Oxalic Acid
  • Paramagnetic Resonance
  • Physical Chemistry

Fields of Study

  • Chemistry

Readers

  • Polymer Science and Technology
  • Surface Engineering/Surface Coating Technology.
  • Systems Analysis and Design