Correlation of the Vibrations of Molecules and Stability in Energetic Materials

Abstract

The paper represents implementation and refinement of the capabilities required to characterize fundamental processes in energetic materials. In particular, attention is focused on the correlation of interatomic forces and physical and chemical instability as manifested by changes in the dynamics of molecular groups in ammonium nitrate, ammonium perchlorate and the metal-azide salts. Results for the compounds are preceded by a discussion of experimental techniques including that of quasi-elastic neutron scattering which has not previously been employed for energetic materials. A brief introduction to the theory of lattice or molecular dynamics is also presented.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1974
Accession Number
AD0785663

Entities

People

  • Chang S. Choi
  • Henry J. Prask
  • Samuel F. Trevino
  • Zafar Iqbal

Organizations

  • Picatinny Arsenal

Tags

Communities of Interest

  • Air Platforms
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Ammonium Perchlorate
  • Crystal Structure
  • Diffraction
  • Energetic Materials
  • Energy
  • Explosives
  • Frequency
  • Frequency Shift
  • Materials
  • Materials Science
  • Measurement
  • Molecular Dynamics
  • Neutron Diffraction
  • Neutron Scattering
  • Phase Transformations
  • Scattering
  • Transition Temperature

Readers

  • Organic Chemistry
  • Quantum Chemistry
  • Systems Analysis and Design