PRODUCTION AND IDENTIFICATION OF HELIUM DIFLUORIDE

Abstract

A program to produce and identify the helium difluoride molecule is summarized in this report. Nine tritiated samples wer produced during the program; new IR absorption peaks found in two samples suggest that tritium decay is producing observable changes. It appears too soon to assign these new peaks to helium-compound formation. Experiments during the program indicated it is possible to detect helium-containing compounds in samples containing as little as one-half curie of tritium. The beta decay tritium in a bifluoride-containing specimen was followed by infrared spectrophotometry for evidence of the conversion of F-T-F ions into F-He-F molecules. It was experimentally determined that the optimum method of producing samples was to mix a small amount of polycrystalline NaHF2 with KBr, and cold-press the mixture into transparent pellets. The nine tritiated samples produced under this contract were fully encased to prevent the escape of radioactive material.

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1966
Accession Number
AD0800497

Entities

People

  • Alan R. Miller

Organizations

  • Aerojet Rocketdyne Holdings

Tags

Communities of Interest

  • Biomedical
  • Weapons Technologies

DTIC Thesaurus Topics

  • Absorption
  • Abstracts
  • Beta Decay
  • Chemistry
  • Contracts
  • Crystals
  • Diffractometers
  • Fabrication
  • Hydrogen
  • Infrared Spectra
  • Materials
  • Measurement
  • Partial Pressure
  • Pressure Measurement
  • Radioactive Materials
  • Spectra
  • Spectroscopy

Fields of Study

  • Physics

Readers

  • Materials Science and Engineering.
  • Solar Physics
  • Underwater engineering and Marine Technology.