FUNDAMENTAL STUDIES IN ELECTROCHEMISTRY.
Abstract
The electrochemical reductions and oxidations of tributyl phosphine, dibutyl chlorophosphate, ethyl dichlorophosphate, dipropyl chlorothiophosphate, di-isopropyl fluorophosphate, triphenyl phosphine oxide, bis-(p-nitrophenyl) phosphate, and triphenyl phosphate have been investigated. The chlorophosphates in general, react with mercury to yield electro-oxidizable and reducible species. Oxidation of a species from a reaction of chlorothiophosphate with a solution species appears to involve one electron. A mechanism for the reduction of triphenyl phosphine oxide and the nature of adsorption process involved in the prewave of bis-(p-nitrophenyl) phosphate are discussed. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Dec 25, 1966
- Accession Number
- AD0812366
Entities
People
- Allen J. Bard
- Bruce Campbell
- K. S. V. Santhanam
Organizations
- University of Texas at Austin