DEPOSITION OF TUNGSTEN BY REDUCTION OF THE HEXAFLUORIDE WITH HYDROGEN IN THE VAPOR PHASE: PROCESS VARIABLES AND PROPERTIES OF THE DEPOSIT.

Abstract

An investigation of the variables involved in the deposition of tungsten from a mixture of tungsten hexafluoride and hydrogen has shown that the temperature of the substrate and the concentration of tungsten hexafluoride are the most important variables. The presence of hydrogen fluoride or chloride in the reacting gases diminished the rate of deposition. The deposits had about the same hardness, electrical conductivity and density as commercial wrought tungsten but had a higher purity. The tensile strength of the deposits was about 30,000 lb/sq in. and the stress within the deposits was of about the same magnitude. Codeposition of carbon, from carbon monoxide, greatly increased the hardness of the deposits. (Author)

Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1967
Accession Number
AD0815459

Entities

People

  • Abner Brenner
  • Jean F. Berkeley
  • Walter E. Reid Jr

Organizations

  • National Institute of Standards and Technology

Tags

DTIC Thesaurus Topics

  • Carbon Monoxide
  • Chemical Compounds
  • Chlorides
  • Conductivity
  • Dielectric Gases
  • Electrical Conductivity
  • Fluorides
  • Gases
  • Hardness
  • Hydrogen
  • Monoxides
  • Phase
  • Physical Properties
  • Tensile Strength
  • Tungsten
  • Vapor Phases

Readers

  • Materials Science and Engineering.
  • Thin Film Deposition Science.