RELAXATION BY VIBRATION-VIBRATION EXCHANGE PROCESSES.
Abstract
A comparative study is presented on the relaxation of harmonic and anharmonic oscillators through vibration-vibration exchange processes. The harmonic model is concluded to be inadequate to describe vibration-vibration exchange since the small anharmonicity associated with real molecules has profound effects on both the dynamic behavior and the steady state distributions resulting in the relaxation of initially non-equilibrium vibrational distributions. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Apr 01, 1967
- Accession Number
- AD0816026
Entities
People
- Edward R. Fisher
- Ralph H. Kummler
Organizations
- General Electric