TITANIUM COMPLEXES OF PARA-SUBSTITUTED PYRIDINE-N-OXIDES. I. EFFECT OF SUBSTITUENT ON THE N-O AND TI-O STRETCHING VIBRATIONS.

Abstract

Para-substituted pyridine-N-oxides and their titanium tetra-fluoride complexes have been studied in the infrared in the region 4000 - 33 cm(-1). Particular attention has been paid to shifts occurring in both the N-O and Ti-O stretching mode as a function of para-substituent. Correlation of both these vibrational modes with the substituent constant reveal that little, if any, back bonding occurs between the titanium atom and the ligands. (Author)

Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1967
Accession Number
AD0823643

Entities

People

  • Frank E. Dickson

Organizations

  • Carnegie Mellon University

Tags

DTIC Thesaurus Topics

  • Chemical Compounds
  • Fluorides
  • Pyridines
  • Titanium
  • Vibration

Fields of Study

  • Chemistry

Readers

  • Materials Science and Engineering.
  • Quantum Chemistry