STUDIES IN SOLUTION PHOTOCHEMISTRY.
Abstract
The photoreactions of aromatic anils have been investigated. These reactions, carried out in NMR tubes, were monitored by NMR. The most important conclusion was that cyclization was not a necessary occurrence during photodegradation. Cis configurations promoted photodegradation. In an analogous system, diphenylamine underwent a photoreaction in CDCl3, but did not photocyclize. The atmosphere over the solution in the NMR tube had an effect on the resolution in the spectrum; outgassed solutions gave spectra of the best resolution. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 01, 1968
- Accession Number
- AD0826476
Entities
People
- Donald D. Rosebrook
Organizations
- MRIGlobal