IRRADIATION OF MEAT PROTEIN.

Abstract

The classical method for extraction and purification of myosin was modified so as to protect the enzyme from oxidation and to prevent actomyosin formation. Using this method, salt solutions of myosin from the sterno mandibularis muscle of the beef animal were prepared. Irradiation of these solutions resulted in rapid aggregation of the protein; adenosine triphosphatase activity increased at doses below 100 Krad while above this level the enzyme was destroyed, the 50% inactivation dose being about 250 Krad. Polyamino acids were used as model compounds in experiments to investigate (1) the effects of radical scavengers on amino acid destruction and amide formation, (2) the exchange of tritium from tritiated water, and (3) interactions with hydrated electrons and hydroxyl radicals. The results of these experiments showed that hydroxyl radicals are responsible for the major part of the destruction. The mechanism of the reactions leading to destruction, the effects of oxygen and the possibility of a 'repair' mechanism involving back-reactions between polyamino acid radicals and hydrated electrons are discussed. In addition, effects of temperature on certain reactions were studied. (Author)

Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1967
Accession Number
AD0827999

Entities

People

  • D. N. Rhodes
  • E. M. Southern

Organizations

  • Agricultural Research Council of South Africa

Tags

DTIC Thesaurus Topics

  • Adenosine
  • Amino Acids
  • Chemical Compounds
  • Electrons
  • Extraction
  • Hydrogen
  • Hydroxyl Radical
  • Oxidation
  • Proteins
  • Super Heavy Water
  • Tritium
  • Water

Readers

  • Molecular and Cellular Biochemistry
  • Nuclear and Radiation Engineering.
  • Organic Chemistry

Technology Areas

  • Microelectronics