Investigations of Mustard Oil Glycosides. 4. Phenyl-Thiourethane-d-Glycoside

Abstract

Particular interest is offered by the decomposition to which phenyl-thio-urethane-d-glycoside is subjected by the influence of water and acids. It assumes here, as it does in respect to its stability, a median position between thiorethane-glycosides synthesized to date on one hand, and the natural mustard oil glycosides (sinigrin, gluco-cheirolin) on the other. While thiourethane-glycosides, aliphatically substituted in connection with nitrogen, decompose and form urethanes and thioglucose, mustard oil glycosides have to date yielded only a cleavage into glucose on one hand, and mustard oil (or its decomposition products) and potassium bisulfate on the other.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1968
Accession Number
AD0843940

Entities

People

  • Douglas Clibben
  • Wilhelm Schneider

Organizations

  • United States Army Biological Warfare Laboratories

Tags

Communities of Interest

  • Air Platforms
  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Acids
  • Alkanes
  • Aqueous Solutions
  • Biological Laboratories
  • Carbonic Acid
  • Decomposition
  • Equations
  • Glycosides
  • Government (Foreign)
  • Governments
  • Hydrogen Sulfides
  • Hydrolysis
  • Melting Point
  • Nitric Acid
  • Silver Compounds
  • Urethanes
  • Water

Fields of Study

  • Chemistry

Readers

  • Analytical Chemistry
  • Marine Ecotoxicology
  • Theoretical Analysis.