Flow Decay: Impaired Flow in Nitrogen Tetroxide Propulsion Systems Caused by Corrosion Product Deposits

Abstract

Flow decay is defined as a condition of impaired flow in nitrogen tetroxide propulsion systems caused by the deposition or the accumulation of stainless-steel corrosion products in small valve orifices or in filters. These corrosion productions take the form of either a solid or a second liquid phase, the latter being variously described as very viscous or gelatinous. Both types of deposit are derived from iron nitrate, the solid being assignable the chemical formula NOFe(NO3)4, the liquid being a complex mixture derived from the interaction of iron nitrate and water. Both are soluble in the nitrogen tetroxide, but only at a level of a few parts per million (as iron). Their presence in the propellant and their deposition is a function of the water equivalent level of the propellant and the temperature and pressure profiles which the propellant encounters before and during flow. In general, the deposition will occur whenever propellant has been cooled just prior to or during flow and this change in temperature required for deposition may be as low as 3 to 5 F.

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Document Details

Document Type
Technical Report
Publication Date
Nov 01, 1968
Accession Number
AD0846606

Entities

People

  • E. F. Cain
  • F. C. Gunderloy Jr.
  • J. Sinor
  • R. I. Wagner

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Air Force
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Engineering
  • Iron
  • Liquid Phases
  • Materials
  • Materials Science
  • Phase
  • Propellants
  • Propulsion Systems
  • Rocket Oxidizers
  • Rocket Propulsion
  • Spectra
  • Stainless Steel
  • Test Methods

Readers

  • Environmental Engineering
  • Rocket Propulsion.
  • Surface Engineering/Surface Coating Technology.