High Char Yielding Nitrosubstituted Epoxide Resins,

Abstract

The thermal properties of a number of nitrosubstituted and analogous nonnitrosubstituted epoxide polymers were investigated. Threefold or more increases in char yield (up to 60%) were obtained on the nitrated analogs. Correspondingly lower maximum rates of weight loss were observed. In one case, this was lowered by 700%. These effects were enhanced when highly functional and highly aromatic epoxide resins were used. The sample size and heating rate employed had pronounced effects upon the amount of char formed during thermal degradation. Analysis of char residues indicates hetero-ring formation for the nitrosubstituted systems during pyrolysis. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jun 16, 1969
Accession Number
AD0856119

Entities

People

  • Gerald J. Fleming

Organizations

  • Naval Ordnance Laboratory

Tags

DTIC Thesaurus Topics

  • Body Weight
  • Chemical Reactions
  • Decomposition
  • Degradation
  • Dissociation
  • Lysis
  • Memory Devices
  • Pyrolysis
  • Thermal Properties

Readers

  • Mathematics or Statistics
  • Organic Chemistry
  • Reinforced Composite Materials