Some Characteristics of Riboflavin Chemiluminescence

Abstract

Data are presented that describe some characteristics of riboflavin chemiluminescence in the dark in the presence of hydrogen peroxide and osmium trichloride. The reaction, in terms of the light intensity produced, is affected by type of buffer, pH, and concentration of reactants. Light intensity is directly proportional to the concentration of riboflavin, and a 1,000-fold increase in relative light intensity is produced when osmium is present. The optimum pH for the reaction in phosphate buffer is 8.0 and in sodium hydroxide, 12. Spectral studies of the riboflavin chemiluminescent reaction show that the emitting species has a maximum intensity of emission at a wavelength different from the fluorescence maximum of riboflavin. The observed 495-millimicron maximum is similar to the maximum observed for the luminescent bacterium, Achromobacter fischeri.

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1969
Accession Number
AD0863653

Entities

People

  • Harold A. Neufeld
  • Philip B. Shevlin
  • Richard D. Towner

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Absorption
  • Absorption Spectra
  • Chemiluminescence
  • Emission Spectra
  • Fluorescence
  • High Voltage
  • Hydrogen
  • Luminescence
  • Maryland
  • Materials
  • New Jersey
  • Photomultiplier Tubes
  • Phototubes
  • Rocket Oxidizers
  • Sodium Hydroxide
  • Spectra
  • United States

Fields of Study

  • Chemistry
  • Physics

Readers

  • Combustion science or combustion engineering.
  • Microbial Pathology
  • Optical Physics and Photonics.