Analysis of Polymers by Pyrolytic Gas Chromatography,

Abstract

Pyrolysis gas chromatography identifies polymers by the composition and concentration of their thermal decomposition products. The pyrolysis may be accomplished by flash-heating or isothermal heating for standard periods of time. The volatile decomposition products are analyzed in packed columns using the appropriate separating phase such as poly(phenyl ether)OS-138. The various separation techniques were evaluated for qualitative reproducibility, quantitative reproducibility, and accuracy. Fingerprinting of polyethylene, polypropylene, polyethylene-polypropylene copolymer, and (Si(CH3)2) n was described to provide examples. This review was prepared on the basis of references in the literature. (Author)

Document Details

Document Type
Technical Report
Publication Date
Apr 17, 1970
Accession Number
AD0869508

Entities

People

  • Tamas Garzo
  • Tamás Székely

Organizations

  • National Air and Space Intelligence Center

Tags

DTIC Thesaurus Topics

  • Accuracy
  • Chromatography
  • Copolymers
  • Decomposition
  • Dielectric Polymers
  • Ethers
  • Gas Chromatography
  • Phenyl Ether
  • Polymers
  • Polypropylene
  • Pyrolysis
  • Reproducibility

Fields of Study

  • Chemistry

Readers

  • Environmental Engineering
  • Life Cycle Cost Analysis
  • Polymer Science and Engineering.

Technology Areas

  • Microelectronics