Electrolytic Ignition System for a Millipound Thruster

Abstract

The objective was the selection of an electrolyte and electrode materials for an electrolytic ignition system for millipound thrusters. This report describes the evaluation of electrode polarization effects, ohmic effects due to both electrolytes and electrodes, and possible catalytic effects on electrode surfaces. Electrical conductivity measurements indicate that hydrazine-based salts must be added to hydrazine in order to minimize ohmic effects and that the mixture of 77% hydrazine-23% hydrazine azide is the most promising electrolyte candidate. Polarization studies have shown that platinum or pyrolytic graphite should be the best anode material for the electrolytic cell and that AM350 or 304SS should be the best cathode material in terms of minimizing the power needs for the cell. These electrodes were also found to catalyze the propellant decomposition reaction in addition to providing simple electrolytic decomposition. This result indicates that the reaction will be self-propagating at power inputs considerably below theoretical.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1971
Accession Number
AD0879878

Entities

People

  • Charles T. Brown

Organizations

  • United Technologies Corporation

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Air Force
  • Anodic Polarization
  • Chemical Reactions
  • Chemistry
  • Contracts
  • Decomposition
  • Electrical Conductivity
  • Electrodes
  • Ignition Systems
  • Materials
  • Materials Science
  • Measurement
  • Photoelectrochemical Cells
  • Polarization
  • Propellants
  • Rocket Oxidizers
  • Test And Evaluation

Fields of Study

  • Materials science

Readers

  • Aerospace Propulsion Engineering.
  • Combustion science or combustion engineering.
  • Electrochemical Engineering/ Fuel Cell Technologies

Technology Areas

  • Space
  • Space - Hall-Effect Thruster