Design Criteria for Inert or Consumable Polymer Cartridge Materials

Abstract

Semiempirical theory is used to provide guidelines for selecting inert or consumable polymer cartridge materials on the basis of chemical, thermal, and mechanical properties for use in existing gun systems. Internal ballistic parameters are obtained using the Le Duc velocity approximation. Resulting energy release, temperature, and transient pressure to the cartridge are then related to rate of degradation, heat transfer, and viscoelasticity in terms of chemical, thermal and mechanical properties using the Arrhenius activation energy theory, and Fourier heat conduction equation, and the Tresca failure criteria. The design criteria are based on simultaneous mechanical failure (powder gas erosive action) and burning/ degradative consumption of a filled or unfilled polymeric cartridge material as a function of the time of projectile travel in the gun. The technique for defining the ideal cartridge material property envelope is outlined for any existing gun system. Candidate polymer cartridge materials on one side of the envelope are consumed on firing, whereas those on the other side are inert. The usefulness of the technique is shown for a specific ammunition in a 5-inch 54-caliber Navy gun.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1971
Accession Number
AD0887364

Entities

People

  • Anthony San Miguel

Organizations

  • Naval Air Weapons Station China Lake

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Ammunition
  • Cartridge Cases
  • Chemical Properties
  • Design Criteria
  • Elastic Properties
  • Energy
  • Failure Mode And Effect Analysis
  • Heat Of Activation
  • Heat Transfer
  • Interior Ballistics
  • Isotherms
  • Materials
  • Materials Science
  • Mechanical Properties
  • Projectiles
  • Test And Evaluation
  • Weapons

Fields of Study

  • Materials science

Readers

  • Polymer Science and Engineering.
  • Rocket Propulsion.
  • Structural Dynamics.